Topic 18 Acids and bases HL
18.1 Lewis theory of acids and bases
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Understandings:
A Lewis acid is a lone pair acceptor and a Lewis base is a lone pair donor. When a Lewis base reacts with a Lewis acid a coordinate bond is formed. A nucleophile is a Lewis base and an electrophile is a Lewis acid. |
18.1 Lewis theory vs Bronsted-Lowry theory
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Guidance:
Relations between Brønsted–Lowry and Lewis acids and bases should be discussed. This video is a comparison between the Lewis theory and the Bronsted-Lowry theory of acids and bases. |
18.2 Temperature dependence of Kw
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Guidance:
This video covers the effect of temperature on the value of the Kw. |
18.2 Acid and base dissociation constants (Ka and Kb)
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Understandings:
The expression for the dissociation constant of a weak acid (Ka) and a weak base (Kb). |
18.2 Calculating the Ka or Kb of a weak acid or base
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This video covers how to calculate the Ka or Kb of a weak acid or base.
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18.2 Ka, pKa, Kb, pKb, Kw, pKw
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Understandings:
For a conjugate acid base pair, Ka × Kb = Kw. The relationship between Ka and pKa is (pKa = -log Ka), and between Kb and pKb is (pKb = -log Kb). Applications and skills: Discussion of the relative strengths of acids and bases using values of Ka, pKa, Kb and pKb. |
18.2 Calculating pH of weak acids and bases
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Applications and skills:
Calculations involving pH, pOH, Ka and Kb. |
18.3 pH curves
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Understandings:
The characteristics of the pH curves produced by the different combinations of strong and weak acids and bases. Applications and skills: The general shapes of graphs of pH against volume for titrations involving strong and weak acids and bases with an explanation of their important features. |
18.3 pH curves part 2
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Understandings:
The buffer region on the pH curve represents the region where small additions of acid or base result in little or no change in pH. Applications and skills: Only examples involving the transfer of one proton will be assessed. Important features are: intercept with pH axis equivalence point buffer region points where pKa = pH or pKb = pOH. |
18.3 Salt hydrolysis
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Applications and skills:
Prediction of the relative pH of aqueous salt solutions formed by the different combinations of strong and weak acid and base. |
18.3 Acid-base indicators
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Understandings:
An acid–base indicator is a weak acid or a weak base where the components of the conjugate acid–base pair have different colours. Applications and skills: Selection of an appropriate indicator for a titration, given the equivalence point of the titration and the end point of the indicator. |
18.3 Buffer solutions
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Understandings:
The composition and action of a buffer solution. Applications and skills: While the nature of the acid–base buffer always remains the same, buffer solutions can be prepared by either mixing a weak acid/base with a solution of a salt containing its conjugate, or by partial neutralization of a weak acid/base with a strong acid/base. |